ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Dependence of Slater-Condon parameters on electron configuration. III. Integrals F⁰(4p,4p), F²(4p,4p), R¹(4s,3d,3d,3d), R¹(4s,4p,4p,3d), and R²(4s,4p,3d) for elements of the first transition series

P. Pelikán, M. Liška, R. Boča, and L. Turi Nagy

Department of Physical Chemistry, Slovak Technical University, 88037 Bratislava

Abstract: There is proposed a method of calculation of values of the integrals F⁰(4p,4p), F²(4p,4p), R¹(4s,3d,3d,3d), R¹(4s,4p,4p,3d), and R²(4s,4p,3d)   in dependence on electron configuration of atoms (ions) of the first transition series. The obtained values of individual integrals are consistent with values of other Slater—Condon parameters obtained by analysis of atomic spectra.

Full paper in Portable Document Format: 325a607.pdf

Chemical Papers 32 (5) 607–615 (1978)