ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Redox Reactions of Iron(III) Chloro and Isothiocyanato Complexes with Triphenylstilbene and Triphenylbismuthine in Acetonitrile

V. Vančová and I. Ondrejkovičová

Department of Inorganic Chemistry, Faculty of Chemical Technology, Slovak Technical University, CS-812 37 Bratislava

Abstract: The reduction of Fe(III) to Fe(II) in the systems FeX₃-EPh₃-acetonitrile (X = Cl, NCS; E = Sb, Bi; Ph = phenyl) occurs at ambient temperature. Fe(II)-Fe(III) complexes of the composition [Fe(NCCH₃)₆][FeX₄]₂ are formed and the ligands EPh₃ are oxidized under formation of XEPh₃.

Full paper in Portable Document Format: 466a382.pdf

Chemical Papers 46 (6) 382–384 (1992)