ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Reaction of 3-0-Benzoyl-1,2-0-isopropyľidene-α-Dxylofuranurononitrile with Phenylmagnesium Bromide

M. Koóš, B. Steiner, and J. Alföldi

Institute of Chemistry, Slovak Academy of Sciences, SK-842 38 Bratislava

Abstract: Reaction of 3-O-benzoyl-1,2-O-isopropylidene-α-D-xylofuranurononitrile with phenylmagnesium bromide in the mole ratio of 1 : 3 afforded 5 benzamido-5-deoxy-5,5-diphenyl-1,2-O-isopropylidene-α-D-xylofuranose. Its structure was proved by special NMR techniques. The imine expected from the addition reaction of Grignard reagent on the nitrile group was not isolated.

Full paper in Portable Document Format: 486a426.pdf

Chemical Papers 48 (6) 426–428 (1994)