ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Preparation and performance analysis of GdInO₃:Eu³⁺ phosphor for solid state lighting applications

Yuanyuan Lu, Zhao Li, Yan Zhang, Kunyao Wu, Yanan Wang, and Man Yu

School of Materials Engineering, Xihang University, Xi’an, China

E-mail: luyuanyuan85@163.com

Received: 24 December 2024  Accepted: 27 May 2025

Abstract:

In the present study, novel hexagonal GdInO₃:Eu³⁺ red phosphors were prepared by a high-temperature solid-state method. Their phase composition, microscopic morphology and luminescence properties were characterized using X-ray diffraction, scanning electron microscopy and photoluminescence spectroscopy. The results indicated that the crystal structure of the matrix material was unaffected by the doping of different concentrations of Eu³⁺. The GdInO₃:Eu³⁺ phosphors existed as irregular micro-sized polyhedra. They emitted 630 nm red light when excited by 395 nm ultraviolet and 467 nm blue light sources. The optimal doping content of Eu³⁺ was found to be 0.07 and the corresponding color coordinates of GdInO₃:0.07 Eu³⁺ phosphor were (0.6426, 0.3510), with a fluorescence lifetime of 1.839 ms and activation energy (ΔE) of 0.15 eV. A white light-emitting diode (LED) was prepared by mixing this red phosphor with commercially available blue and green phosphors, which exhibited remarkable white light emission. The chromaticity coordinates of the prepared device were (0.3638, 0.3481) with a color rendering index of 83.5. The results demonstrated that GdInO₃:Eu³⁺ is a good red light-emitting material, which can be utilized in white LEDs.

Keywords: High-temperature solid-phase method; Blue-light excitation; GdInO3:Eu3+; Photoluminescence

Full paper is available at www.springerlink.com.

DOI: 10.1007/s11696-025-04156-8

Chemical Papers 79 (9) 5831–5841 (2025)