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ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Published monthly
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Synthesis of a disulfide functionalized diacetylenic derivative of carbazole as building-block of polymerizable self-assembled monolayers
Sushilkumar A. Jadhav and Massimo Maccagno
Department of Applied Science and Technology, Polytechnic University of Turin, 10129, Turin, Italy
E-mail: sushilkumar.jadhav@polito.it
Abstract: A new symmetrical disulfide containing a diacetylenic unit and bearing a fluorescent carbazolyl end-group forming polymerizable self-assembled monolayers on metallic nanostructures has been synthesized. Suitable modifications of the synthetic steps involved in the synthesis of such derivatives were made in order to assure better synthetic pathway. Conversion of the tosylated derivative into the final symmetrical disulfide is carried out using sodium hydrosulfide (NaSH).
Keywords: symmetrical disulfide – diacetylene – sodium hydrosulfide
Full paper is available at www.springerlink.com.
DOI: 10.2478/s11696-013-0437-2
Chemical Papers 68 (2) 239–245 (2014)
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