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Synthesis and electronic spectra of l-aryI-2-řerrocenylethyIenes

Š. Тoma, A. Gálpovský, and T. Elečko

Department of Organic Chemistry, Faculty of Natural Sciences, Komenský University, CS-842 15 Bratislava

 

Abstract: Fourteen l-aryl-2-ferrocenylethyIenes were synthesized from ferrocene and substituted phenylacetic acids. Those bearing electron-accepting groups were prepared by Wittig reaction from ferrocenylmethyltriphenylphosphonium iodide and aromatic aldehydes. Relationship between the electronic spectra, especially of the so-called d—d band at about 440 nm and the effect of substituent of the title products was investigated.

Full paper in Portable Document Format: 391a115.pdf

 

Chemical Papers 39 (1) 115–124 (1985)

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