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The spectrophotometric research of chlorocupric complexes in acetone. IV

J. Gažo

Slovak Technical University, Bratislava

 

Abstract: cf. C.A. 51, 10292e. The spectrophotometric study was made on the systems CuCl2-LiCl or NaCl or KCl or CsCl-acetone. All chlorides in acetone solns. of CuCl2 shift the equil. in the direction of the formation of chlorocupric complexes. A modified method of limiting logs was developed to prove the coexistence of Cu-Cl3- with CuCl4--. The results agreed with the methods of Ostromuislenskii (C.A. 5, 1702) and of Job (C.A. 22, 2120).

Full paper in Portable Document Format: 113a143.pdf (in Slovak)

 

Chemical Papers 11 (3) 143–149 (1957)

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