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The aging of the system Cu2+-Cl--Br--acetone

J. Gažo and T. Šramko

Slovak Technical University, Bratislava

 

Abstract: A method for the detn. of the decrease of the concn. of Cu2+ by reduction to Cu+ in the system Cu2+-Cl--Br--Me2CO is described. It has been shown experimentally that aging in this system is caused by the oxidation-reduction process as well as by other processes. Bromocupric complexes are changed by the oxidation-reduction process, and the concn. of [CuCl3Br]-- ions is decreased as a result of the substitution of Cl atoms by Br atoms.

Full paper in Portable Document Format: 1111a633.pdf (in Slovak)

 

Chemical Papers 11 (11) 633–640 (1957)

Thursday, January 20, 2022

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