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ISSN electronic edition: 1336-9075
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Effect of radiation on the halogenating activity of halocopper(II) and haloiron(III) complexes

G. Ondrejovič, J. Čislovová, and Ján Gažo

Slovak Technical University, Bratislava

 

Abstract: The effect of light on the halogenating activity of halocopper(II) and haloiron(III) complexes in Me2CO and acrylonitrile (I) in relation to the oxidn.-redn. processes and to the mutual effect of ligands was studied. Properties of the following systems were studied: CuCl2-Me2CO, CuCl2-LiCl-Me2CO, CuCl2-I, CuBr2-I, CuCl2-LiCl-I, FeCl3-I, and FeCl3-LiCl-I. Light increases the halogenating activity in the same way as does the mutual effect of the ligands in the heterogeneous complexes in these systems.

Full paper in Portable Document Format: 2010a729.pdf (in Slovak)

 

Chemical Papers 20 (10) 729–737 (1966)

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