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Mixed cyanonickel(II) complexes. I. Preparation and properties of dicyanoaquothiosemicarbazidenickel(II)

T. Šramko and J. Kohout

Department of Inorganic Chemistry, Slovak Technical University, Bratislava

 

Abstract: Heterogeneous nickel complexes with thiosemicarbazide and cyanide group of molecular formulae Ni(CN)2thio. H20 and Ni(CN)2thio were prepared.  The magnetic properties, absorption and diffuse reflectance spectra, infra-red absorption spectra and some thermic properties were studied. The results of measurements are characteristic for a diamagnetic square-planar complex, stabile even in aqueous solution.

Full paper in Portable Document Format: 219a698.pdf (in Slovak)

 

Chemical Papers 21 (9) 698–705 (1967)

Thursday, January 20, 2022

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