ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

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Infrared Spectra of Some Azido Derivatives of Methylpentopyranosides

J. Alföldi and C. Peciar

Department of Analytical Chemistry, Institute of Chemistry, Slovak Academy of Sciences, Bratislava 9

 

Abstract: Eleven azido derivatives of methylpentopyranosides were studied by infrared spectroscopy in the 2100 — 2230 cm-1 region. The azido group absorption band was found to be split. Since no effect of the physical state of samples on the band splitting could be observed, this is ascribable to Fermi resonance. Other experimental data confirmed that the position of the azido group absorption band is associated with its stereochemical orientation in azido derivative molecule.

Full paper in Portable Document Format: 235a352.pdf

 

Chemical Papers 23 (5) 352–355 (1969)

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