ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Hydroformylation of α,β-unsaturated acid esters
E. J. Mistrík and J. Durmis
Forschungsinstitut für Petrolchemie, Nováky
Abstract: A hydroformylation of acrylic and metacrylic acid esters was investigated.
The rate of hydroformylation is dependent on the ester alkyl group
on the multiple bond carbon substituents, as well.
The competition reaction which comes into play in hydroformylation
reaction to greatest extent is the hydrogenation of β-formylester and lactonization
γ-hydroxy ester. The lactonization process of methyl aery late and
methyl metacrylate and yields of lactons were compared at various temperatures.
Full paper in Portable Document Format: 234a286.pdf (in German)
Chemical Papers 23 (4) 286–294 (1969)
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