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Copper(II) and cobalt(II) hydroxypyridinecarboxylates: Synthesis, crystal structures, spectral and magnetic properties

Jozef Miklovič, Peter Segľa, Dušan Mikloš, Ján Titiš, Radovan Herchel, and Milan Melník

Department of Chemistry, Faculty of Natural Sciences, University of St. Cyril and Methodius, 917 01 Trnava, Slovakia

 

E-mail: jozef.miklovic@ucm.sk

Received: 17 December 2007  Revised: 18 February 2008  Accepted: 20 February 2008

Abstract: Synthesis and characterization of six copper(II) and cobalt(II) octahedral complexes [M(6-OHpic)2(H2O)2] (6-OHpic is 6-hydroxypicolinato), [M(2-OHnic)2(H2O)2] (2-OHnic is 2-hydroxynicotinato), [Cu(6-OHnic)2(H2O)2] (6-OHnic is 6-hydroxynicotinato) as well as [Co(H2O)6](6-OHnic)2 are reported. Their characterization was carried out using elemental analysis, infrared, and magnetic measurements. Based on IR spectra, N,O-coordination of 6-OHpic (via the oxygen atom of the carboxyl group and the nitrogen atom of the pyridine ring), O,O-asymmetrically chelating coordination of the carboxyl groups as well as ionic coordination of 6-OHnic and chelating O,O-coordination (through the oxygen atom of the carboxyl group and the oxygen atom of the amide group) of keto(amide) tautomer of 2-OHnic were supposed. Moreover, crystal structures of 2-OHnicH and the complex [Co(2-OHnic)2(H2O)2]) were determined by X-ray single crystal structure analysis. The system of hydrogen bonds predominantly stabilizes the keto(amide) tautomer of both 2-hydroxynicotinic acid and 2-OHnic anion in the cobalt(II) complex. Intermolecular hydrogen bonds (between the oxygen atom of the amide group and the hydrogen atom of the NH group) interconnect two neighbouring molecules of 2-OHnicH forming dimers. Cobalt(II) in complex [Co(2-OHnic)2(H2O)2] has nearly a regular compressed tetragonal bipyramidal arrangement.

Keywords: Cu and Co complexes - hydroxypyridinecarboxylate - crystal structure - spectral properties

Full paper is available at www.springerlink.com.

DOI: 10.2478/s11696-008-0056-5

 

Chemical Papers 62 (5) 464–471 (2008)

Wednesday, September 23, 2020

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