ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Vibrational spectra of vanadium(V) compounds. II.
Vibrational spectra of divanadates with nonlinear bridge VOV
P. Schwendt and D. Joniaková
Department of Inorganic Chemistry, Faculty of Natural Sciences,
Komenský University, 801 00 Bratislava
Abstract: The vibrational spectra of α-Zn2V2O7, Mg2V2O7, and Pb2V2O7 were
measured and assigned. Difference between wavenumbers of stretching
vibrations of bridge bonds decreases monotonously with the angle V-O-V.
The value of the difference can be used in order to estimate the configuration
of bridge in divanadates, M2V2O7.
Full paper in Portable Document Format: 293a381.pdf
Chemical Papers 29 (3) 381–386 (1975)
Friday, September 30, 2022