ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Basicity of hydroxylamine and its derivatives

J. Mollin, F. Kašpárek, and J. Lasovský

Department of Inorganic and Physical Chemistry, Faculty of Natural Sciences, Palacký University, 771 46 Olomouc

Abstract: The рК_а. values of hydroxylamine and its derivatives were determined titrimetrically in water and water — ethanol mixtures. The obtained  рК_а values of the O-alkylhydroxylamines were correlated with the half-wave potentials of the Polarographie reduction waves. A surprisingly high рК_а value of hydroxylamine was explained on the basis of the formation of hydrogen bonds with solvent proved by means of infrared spectra.

Full paper in Portable Document Format: 291a39.pdf

Chemical Papers 29 (1) 39–43 (1975)