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Relations among standard potentials in electrochemical systems of type M, Ma+, Mb+

A. Reháková

Lehrstuhl für Mathematik der Slowakischen Ökonomischen Hochschule, 886 33 Bratislava

 

Abstract: The title systems are theor. analyzed. In the electrochem. systems formed by the metal M and its ions Ma+ and Mb+ (0 < a < b), 3 std. potentials i.e. Ea/0, Eb/0, and Eb/a exist and may be arranged in 2 ways in resp. to their relative magnitudes. The validity of these 2 modes of arrangement were proven without the use of the Luther equation: bE°b/0 = aE°a/0 + (b-a) E°b/a.

Full paper in Portable Document Format: 306a832.pdf (in German)

 

Chemical Papers 30 (6) 832–840 (1976)

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