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Thermal decomposition of ammonium cadmium decavanadate

Ľ. Ulická

Department of Inorganic Chemistry, Faculty of Natural Sciences, Komenský University, 801 00 Bratislava

 

Abstract:  This paper is concerned with the thermal decomposition of decavanadate of the composition (NH4)4CdV10O28 . 14H2O. By X-ray phase analysis and infrared spectro­scopy it was found that this compound decomposed even before the completion of dehydration to give other polyvanadates. The decomposition reaction proceeded in several steps, the final product being a mixture of vanadium(V) oxide and cadmium metavanadate.

Full paper in Portable Document Format: 304a409.pdf

 

Chemical Papers 30 (4) 409–415 (1976)

Thursday, March 28, 2024

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