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Dependence of Slater-Condon parameters on electron configuration. III. Integrals F0(4p,4p), F2(4p,4p), R1(4s,3d,3d,3d), R1(4s,4p,4p,3d), and R2(4s,4p,3d) for elements of the first transition series

P. Pelikán, M. Liška, R. Boča, and L. Turi Nagy

Department of Physical Chemistry, Slovak Technical University, 88037 Bratislava

 

Abstract: There is proposed a method of calculation of values of the integrals F0(4p,4p), F2(4p,4p), R1(4s,3d,3d,3d), R1(4s,4p,4p,3d), and R2(4s,4p,3d)   in dependence on electron configuration of atoms (ions) of the first transition series. The obtained values of individual integrals are consistent with values of other Slater—Condon parameters obtained by analysis of atomic spectra.

Full paper in Portable Document Format: 325a607.pdf

 

Chemical Papers 32 (5) 607–615 (1978)

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