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Kinetics of alkaline hydrolysis of the 2-piperidinoethyl esters of o-, m-, and p-alkoxyphenylcarbamic acids

M. Stankovičová, J. Čižmárik, and M. Pešák

Department of Pharmaceutical Chemistry, Faculty of Pharmacy, Komenský University, 880 34 Bratislava

 

Abstract:  The rate constants of alkaline hydrolysis have been determined at 60°C for a series of the basic esters of alkoxyphenylcarbamic acids. The values of  ΔΔG have been calculated and the relationships log k =f(σ) and ΔΔG = f(σ) have been determined for some m- and p -derivatives.

Full paper in Portable Document Format: 321a86.pdf

 

Chemical Papers 32 (1) 86–91 (1978)

Monday, July 26, 2021

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