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Problem of liquid junction potential in molten salt solutions

J. Josiak and J. Terpilowski

.Department of Inorganic Chemistry, Institute of Chemistry and Technology of Medicinal Products, 50-139 Wroclaw

 

Abstract: Diffusion potential measurements for SnCl2-SnBr2, SnCl2-SnI2, PbCl2-PbBr2, and PbCl2-PbI2 fused systems were carried out by means of detn. of the emf. of anionic concn. cells. The measured values of diffusion potentials permit to suppose that the transport nos. of the anions, Cl- and Br- or Cl- and I- change proportionally to the mole fractions of corresponding salts.

Full paper in Portable Document Format: 333a329.pdf

 

Chemical Papers 33 (3) 329–334 (1979)

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