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Substitution of hydrogen by deuterium hindering the biochemical dehydrogenation of alditols in the sense of the Bertrand-Hudson rule

Ľ. Stankovič, V. Bílik, L. Petruš, and V. Kováčik

Institute of Chemistry, Slovak Academy of Sciences, 809 33 Bratislava

 

Abstract: The biochem. dehydrogenation by Acetobacter pasteurianus BS 1775 of D-arabinitols labeled with D in the C-4 position does not proceed. Similarly, the reaction was totally blocked with D-[4-2H]ribitol. The D-[2-2H]mannitol which has theor. 2 reaction centers was dehydrogenated only at the C-5 position.

Full paper in Portable Document Format: 345a695.pdf

 

Chemical Papers 34 (5) 695–699 (1980)

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