ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
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Thermal decomposition of potassium μ-oxo- and μ-hydroxo-bis(oxodiperoxovanadate)

P. Schwendt and D. Úškert

Department of Inorganic Chemistry, Faculty of Natural Sciences, Komenský University, 816 31 Bratislava

 

Abstract: In the systematic study of slow decompn. of V(V) peroxo compds., the products of thermal reactions of K4[V2O3(O2)4].2H2O and K3[HV2O3(O2)4].H2O were studied under conditions which did not allow a rapid liberation of peroxidic O. The decompn. intermediates react with CO2 present in air and the final products of decompn. of both compds. are KVO3 and K3[VO(O2)2(CO3)].

Full paper in Portable Document Format: 352a229.pdf

 

Chemical Papers 35 (2) 229–233 (1981)

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