ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

Published monthly
 

Structure of bis(triethylammonium) bromochlorocuprates(II) as a function of their composition

Z. Biela and J. Gažo

Department of Inorganic Chemistry, Slovak Technical University, 880 37 Bratislava

 

Abstract: Compounds  [(C2H5)3NHl2CuCl4 (I), [(C2H5)3NH]2CuCl3Br (II), [(C2H5)3NH]2CuCl2Br2 (III),  [(C2H5)3NH]2CuClBr3 (IV), and [(C2H5)3NH]2CuBr4 (V) were prepared by crystallization from ethanolic solutions. Changes in the composition of the complexes were accompanied by changes in the structure of the coordination polyhedron from a distorted tetrahedron of various degree of distortion up to a distorted octahedron. In consonance with this fact, the d—d transition energies as well as the values of the g factors correspond to a compressed tetrahedron in the case of compounds J, II, and III, and to an elongated octahedron in the case of compounds IV and V.

Full paper in Portable Document Format: 352a215.pdf

 

Chemical Papers 35 (2) 215–222 (1981)

Thursday, February 25, 2021

IMPACT FACTOR 2019
1.680
SCImago Journal Rank 2019
0.331
SEARCH
Advanced
VOLUMES
XXVIII. International Conference on Coordination and Bioinorganic Chemistry
© 2021 Chemical Papers