ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Axial versus equatorial metal-ligand distances in transition metal compounds. II. Hexanitro complexes
Department of Inorganic Chemistry, Slovak Technical University,
880 37 Bratislava
Abstract: Hexanitro complexes of CoII, NiII, and CuII represent systems under investigation. They exhibit phase transitions depending on temperature. The central
atom—ligand distances in these square-bipyramidal complexes correlate in the
way that with increasing axial distance, Ra, the value of equatorial central
atom—ligand distance, Re, decreases and vice versa. Thus the so-called Ra vs.
Re dependence is registered within the individual compounds as a consequence
of changes in the amount of the total energy.
Full paper in Portable Document Format: 356a779.pdf
Chemical Papers 35 (6) 779–784 (1981)