ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
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Axial versus equatorial metal-ligand distances in transition metal compounds. I. Hexafluoro complexes

R. Boča

Department of Inorganic Chemistry, Slovak Technical University, 880 37 Bratislava

 

Abstract: X-ray structural data of the 1st-row transition metal hexafluorides were analyzed. Mean equatorial, Re, and mean axial, Ra, metal-ligand distances exhibit an Ra vs. Re correlation realized in the fact that with increasing Ra the distance Re decreases and vice versa. The studied complexes cover elongated and compressed tetragonal bipyramids having in their octahedral configuration 3 classes of electronic ground states.

Full paper in Portable Document Format: 356a769.pdf

 

Chemical Papers 35 (6) 769–777 (1981)

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