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Spontaneous and photochemical redox reactions of iron(II) and iron(III) bromo complexes in nonaqueous media

H. Zliechovcová, J. Šima, D. Valigura, and J. Sýkora

Department of Inorganic Chemistry, Slovak Technical University, 812 37 Bratislava

 

Abstract: The results of the study of spontaneous and photosensitized oxidation of Fe(II) to Fe(III), as well as the photoreduction of Fe(III) to Fe(II) in the systems of Fe(II) and Fe(III) bromo complexes in the acetone—methanol mixtures are presented. Some kinetic data on the investigated reactions are given and their mechanism is discussed.

Full paper in Portable Document Format: 361a59.pdf

 

Chemical Papers 36 (1) 59–63 (1982)

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