ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

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Study of the interaction in the system poly(2,6-dimethylphenylene oxide)-solvent

P. Pelikán, L. Lapčík, J. Polavka, and V. Kellö

Department of Physical Chemistry, Slovak Technical University, 812 37 Bratislava

 

Abstract:  In the present paper the model interaction of poly(2,6-dimethylphenylene oxide) with various solvents (chloroform, carbon tetrachloride, benzene, toluene, xylenes) is studied. As a model the interaction of 2,6-dimethyl hydroquinone (which reproduces the electron density distribution in poly(2,6-dimethylphenylene oxide) very well) with molecules of individual solvents was used. The semiempirical CNDO/2 method with the limited configuration interaction has been applied for all calculations. Theoretically obtained results were correlated with experimental data.

Full paper in Portable Document Format: 366a761.pdf

 

Chemical Papers 36 (6) 761–771 (1982)

Monday, June 27, 2022

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