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Heteronuclear complex of N-(2-hydroxyethyl)-N-carboxymethylaminoacetohydroxamic acid with copper(II) and iron(III)

R. Karlíček and V. Jokl

Department of Analytical Chemistry, Faculty of Pharmacy, Charles University, CS-501 65 Hradec Králové

 

Abstract: The title compd. forms in solns. with excess Cu ions a binuclear complex [Cu2(L-1H)]+ and in solns. with both Cu and Fe ions it forms a ternary complex [CuFe(L-1H)]2+. In both cases the complex formation is followed by splitting of 2 H ions from 1 carbohydroxamic functional group. Spectrophotometric characteristics and equil. consts. of the individual complexes are presented.

Full paper in Portable Document Format: 372a191.pdf

 

Chemical Papers 37 (2) 191–199 (1983)

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