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Synthesis and properties of photosensitive derivatives of cellulose

G. Čík, V. Lužáková, A. Blažej, J. Goljer, L. Omelka, and T. Marcinčinová

Department of Textile, Pulp, and Paper, Slovak Technical University, CS-812 37 Bratislava

 

Abstract: Some photosensitive derivatives were synthesized by introducing the o-nitroaryl chromophore into polymer chain of acetylated hydroxyethylcellulose (НЕС). The products were characterized viscosimetrically and by u.V., i.r. as well as 13C-n.m.r. spectroscopy. The phototransformation reactions of the synthesized products were investigated. By the effect of ultraviolet radiation acetylated НЕС is subjected to photodestructive and photooxidative transfor­mations. The presence of the o-nitroaryl chromophore enhances the photosen­sitivity of the cellulose derivative.

Full paper in Portable Document Format: 382a273.pdf

 

Chemical Papers 38 (2) 273–284 (1984)

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