ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Electrochemical resolution of cyanide-linkage isomers in the course of the reaction of [Cr(CN)₂(H₂O)₃NO] with  Hg²⁺ ions

M. Rievaj and D. Bustin

Department of Analytical Chemistry, Slovak Technical University, CS-812 37 Bratislava

Abstract: Transformation by semi-differentiation was employed to raise the resolving power off voltammetry with a stationary hanging Hg drop electrode. This technique was applied to analyze components with small differences in halfwave potentials by using the method of subtraction of the peak of 1 component from curve of coinciding peaks for the anal. of intermediates and products of multistep reaction of [Cr(CN)₂(H₂O)₃NO] with Hg²⁺.

Full paper in Portable Document Format: 386a749.pdf

Chemical Papers 38 (6) 749–757 (1984)