ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

Published monthly
 

Preparation and identification of aldolization products of 1,3-dimethoxy-2-propanone

M. Petrušová, V. Mihalov, P. Kočiš, and M. Fedoronko

Institute of Chemistry. Centre for Chemical Research, Slovak Academy of Sciences, CS-842 38 Bratislava

 

Abstract: 4-Hydroxy-1,3,5-trimethoxy-4-methoxymethyl-2-pentanone (11), 4,6-dihydroxy-1,3,5,7-tetramethoxy-4,6-bis(methoxymethyl)-2-heptanone (///,),  and 4,6,8-trihydroxy-1,3,5,7,9-pentarnethoxy-4,6,8-tris(methoxymethyl)-2-nonanone (IV) have been prepared by aldolization of 1,3-dimethoxy-2-propanone (I) in aqueous NaOH solution at 5 'C. The components of the reaction mixture were separated by liquid chromatography and their structures were established by 13C NMR spectroscopy as well as by mass spectrometry after their reduction with NaBD.

Full paper in Portable Document Format: 396a763.pdf

 

Chemical Papers 39 (6) 763–768 (1985)

Monday, July 13, 2020

IMPACT FACTOR 2018
1.680
SCImago Journal Rank 2019
0.331
SEARCH
Advanced
VOLUMES
© 2020 Chemical Papers