ISSN print edition: 0366-6352
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Composition of the fluorooxoperoxo complexes of vanadium(v) crystallizing from acid-medium

P. Schwendt, D. Joniaková, and V. Ezr

Department of Inorganic Chemistry, Faculty of Natural Sciences, Komenský University, CS-842 15 Bratislav


Abstract: Some problems involved in the determination of composition of the fluoro- oxoperoxo complexes of vanadium(V) obtained from acid medium are discus- sed in this paper. Owing to low stability of these complexes, the prepared substances may contain decomposition products, which results in a decrease in content of the peroxidic oxygen and formulation of the obtained substances as complexes with the ratio n(Ol~)/n(V) = 1. The existence of the fluorooxopero- xo complexes of this type has not been hitherto confirmed.

Full paper in Portable Document Format: 393a353.pdf


Chemical Papers 39 (3) 353–360 (1985)

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