ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Gas chromatography of alkyl N-phenylcarbamates

M. Šingliar, V. Macho, and J. Terlandová

Department of Organic Technology, Faculty of Chemical Technology, Slovak Technical University, CS-97104 Prievidza

Abstract: Methyl, ethyl, up to heptyl N-phenylcarbamates were synthesized and their retention indices were measured by gas chromatography at three column temperatures. The relationship between retention indices and number of carbon atoms in the alkyl of carbamate is linear except for the first member of the homologous series. In gas chromatographic investigations we have to take into consideration that alkyl N-phenylcarbamates and especially tert-butyl N-phenylcarbamate are thermolabile substances.

Full paper in Portable Document Format: 434a519.pdf

Chemical Papers 43 (4) 519–525 (1989)