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Kinetics of Oxidation of Diethylamine by N-Chlorobenzotriazoles

R. Ulagi, P. Kuselan, and C. Karunakaran

Department of Chemistry, LRG Government Arts College for Women,Tirupur 641604, India

 

E-mail: karunakaranc@rediffmail.com

Received: 27 February 2001

Abstract: Kinetics of the oxidation of diethylamine with 1-chlorobenzotriazole, 1-chloro-4-nitrobenzotriazole,and 1,4,5,6,7-pentachlorobenzotriazole in aqueous acetic acid, in the presence of perchloric acid, hasbeen studied. The oxidation is a second-order reaction uncatalyzed by acid. The rates and the activationparameters of the oxidation by the three chloramines do not differ significantly and thechloramines oxidize by a common mechanism.

Full paper in Portable Document Format: 562a123.pdf

 

Chemical Papers 56 (2) 123–126 (2002)

Tuesday, July 23, 2024

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