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Synthesis of Vicinally Substituted by Halogen 4-Methylthio and Methylsulfonyl Derivatives of 2,6-Dimethylpyridine and Their 1-Oxides

H. Ban-Oganowska

Department of Organic Chemistry, Academy of Economics, PL-53 342 Wroclaw

 

Abstract: 3-Halo-2,6-dimethyl-4-nitropyridine 1-oxides react with sodium methanethiotate giving 3-halo-2,6-dimethyl-4-methylthiopyridine 1-oxides which are oxidized into respective methylsulfonyl derivatives and reduced to 3-halo-2,6-dimethyl-4-methylthiopyridines.

Full paper in Portable Document Format: 492a94.pdf

 

Chemical Papers 49 (2) 94–96 (1995)

Thursday, April 22, 2021

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