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Coordination Complexes of 5-Benzyl β-N-(Ferrocenyl)methylenedithiocarbazate

L. Qing-Shan, L. Yong-Min, W. Xiao-Li, and M. Yong-Xiang

National Laboratory of Applied Organic Chemistry, Lanzhou University, 730000 Lanzhou, China

 

Abstract: S-Benzyl β-N-(ferrocenyl)methylenedithiocarbazate (HBfm) and its coordination complexes, M(Bfm)2 . nH2O (M = Cu2+, Ni2+, Co2+, Zn2+, Cd2+, Hg2+ and Mn2+) have been prepared by the reaction of HBfm with the transition metal(II) acetate in ethanol and are characterized by elemental analyses, molar conductivities, IR, NMR, UV spectra, and thermal analyses. The ligand coordinates to central ions in the thio-enolic form with the mole ratio 2:1.

Full paper in Portable Document Format: 505a288.pdf

 

Chemical Papers 50 (5) 288–291 (1996)

Wednesday, February 21, 2024

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