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Kinetics and Mechanism of Reaction of Methoxide Ion with 0-( N-Ary lcarbamoyl) benzophenone Oximes

V. Kožený, J. Mindl, and V. Štěrba

Department of Organic Chemistry, Faculty of Chemical Technology, University Pardubice, CZ-532 10 Pardubice

 

Abstract: A series of nine O-(N-arylcarbamoyl)benzophenone oximes and their two N-methyl derivatives has been prepared and characterized. For estimation of mechanism E1cB of the above-mentioned compounds a new simple competition test using butylamine and kinetic studies were used. Hammett reaction constants for the given reaction ρobs = 0.68 and ρk2  = -1.32 were calculated.

Full paper in Portable Document Format: 511a29.pdf

 

Chemical Papers 51 (1) 29–32 (1997)

Wednesday, September 28, 2022

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