ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Synthesis of terpenylic acid and its analogues by oxidative cleavage and lactonization of cyclopentenyl carbinols

Pham Duy Quang Dao, Jun-Hyun Park, Ho-Jin Lim, and Chan Sik Cho

Department of Applied Chemistry, Kyungpook National University, Bukgu, Republic of Korea

E-mail: cscho@knu.ac.kr

Received: 25 August 2021  Accepted: 1 November 2021

Abstract:

Cyclopentenyl carbinols are oxidatively cleaved and cyclized into a class of terpenylic acid analogues in the presence of oxone and sodium periodate in good yields.

Graphical abstract

Keywords: Terpenylic acid; Oxone; Oxidative cleavage; Lactonization; Cyclopentenyl carbinol

Full paper is available at www.springerlink.com.

DOI: 10.1007/s11696-021-01964-6

Chemical Papers 76 (3) 1885–1889 (2022)